Several naphthalenoferrocenophanes, in which the two cyclopentadienyl rings are linked by two naphthalene rings were synthesized via intramolecular reductive coupling of the corresponding formyl compounds with a low valent titanium reagent.Their structures are deduced from IR, NMR, and UV spectra.Transannular ?-electronic interaction between the two naphthalene rings is discussed on the basis of electronic spectra.