Ligand-free Ni-catalyzed reductive cleavage of inert carbon - Sulfur bonds
A catalytic reductive cleavage of C(sp2) - and C(sp3) - SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches.
Barbero, Nekane,Martin, Ruben
supporting information; experimental part
p. 796 - 799
(2012/04/23)
NOVEL AND EFFECTIVE METHODS FOR α-THIOALKYLATION OF AROMATIC COMPOUNDS
Convenient and effective methods for the introduction of a methylthiomethyl group and other α-thioalkyl group into aromatic compounds are described.
Torisawa, Yasuhiro,Satoh, Atsushi,Ikegami, Shiro
p. 1729 - 1732
(2007/10/02)
ALKYLATION OF AROMATIC COMPOUNDS WITH PUMMERER REARRANGEMENT INTERMEDIATES. APPLICATION TO THE PREPARATION OF METHYL-ARYL COMPOUNDS
Pummerer intermediates generated from dimethylsulfoxide reacted with aromatic compounds in the presence of tin(IV) chloride to give methylthiomethylaryl products which were in turn desulfurized to methylaryl compounds with Raney-Ni.
Stamos, Ioannis K.
p. 2787 - 2788
(2007/10/02)
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