Spin-crossover transition coupled with another solid-solid phase transition for iron(II) thiocyanate complexes chelated with alkylated N-(di-2- pyridylmethylene)anilines
We have prepared spin-crossover [FeL2(NCS)2] complexes chelated with alkylated N-(di-2-pyridylmethylene)anilines. The wider irreversible thermal loop across room temperature was observed with the longer alkyl chain introduced (ΔTsub
Synthesis and properties of nitrogen-introduced phenylazomethine dendrimer
The pyridine ring-introduced phenylazomethine dendrimer (PyDPA) was synthesized by a dehydration reaction using titanium(IV) chloride. The ultraviolet-visible absorption and the electrochemical study showed that the introduction of the pyridine ring produ