- INORGANIC HETEROCYCLE COMPOUNDS AND CHARGE TRANSFER COMPLEXES
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By reduction of sulfur nitride, S4N4, with hydrazine, N2H4, we have prepared all the seven eight-membered ring sufurimines in the crystallized form.However, besides sufurimine crystals, one notes the presence of elongated hexagonal crystals, which are very different in size and morphology.A study of these isolated crystals by: I.Chemical analysis.II.Infrared spectrography and U.V. spectrography.III.Radiocrystallography, shows that they are molecular charge-transfer complexes (C.T.C.), Hydrogen bond type: -> D.+ -> A.- Donor.Acceptor.A few examples are given in Figure 11, in which are reported the chemical, crystallographical and spectroscopic results for solid octahedral sulfur derivatives.
- Garcia-Fernandez, H.
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