A novel one pot synthesis of benzyl sulfides: Samarium-induced, benzyl bromide mediated reduction of alkyl thiocyanates and diaryl disulfides in methanol
A convenient synthesis of benzyl Sulfides by the treatment of alkyl thiocyanates or diaryl disulfides with metallic samarium and benzyl bromide in methanol has been developed.
Zhan, Zhuang-Ping,Lang, Kai
p. 443 - 444
(2007/10/03)
Chemoselective alkylation of thiols: A detailed investigation of reactions of thiols with halides
Arylthiols, aralkylthiols and alkane thiols can be readily alkylated by alkyl/aralkyl halides in presence of K2CO3/DMF to yield unsymmetrical sulphides in nearly quantitative yields. 2-Mercaptoethanol gave the thioether chemoselectively.
Khurana,Sahoo
p. 1691 - 1702
(2007/10/02)
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