Cooperative catalysis by tertiary amino-thioureas: Mechanism and basis for enantioselectivity of ketone cyanosilylation
The mechanism of the enantioselective cyanosilylation of ketones catalyzed by tertiary amino-thiourea derivatives was investigated using a combination of experimental and theoretical methods. The kinetic analysis is consistent with a cooperative mechanism
Zuend, Stephan J.,Jacobsen, Eric N.
p. 15872 - 15883
(2008/10/09)
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