Substituent Constants of the Pyrazol, 1,2,3-Triazol, Benzotriazol, and Naphthotriazol Group
The synthesis of benzoic acids with the title substituents in p- and m-position (15, 13, 11, 9) and their ethyl and methyl esters is described.The ?p and ?m values of the substituents obtained by alkaline hydrolysis of the esters in ethanol/water and methylcellosolve/water demonstrate an inductive electron withdrawing and a mesomer electron donating effect of these groups which are important for dye chemistry.
Sachweh, Volker,Langhals, Heinz
p. 1627 - 1639
(2007/10/02)
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