Treatment of (S)-(+)-1-chloro-2,2-diphenylcyclopropane with n-butyllithium at -25 deg C yield, inter alia, (R)-(-)-1-n-butyl-2,2diphenylcyclopropane with overall inverted configuration.A metal assisted ionization mechanism is proposed.
Walborsky,H.M.,Duraisamy,M.
p. 2743 - 2746
(2007/10/02)
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