Intramolecular Additions of Allylsilanes to Conjugated Dienones. The Synthesis of Three Perforanes
Intramolecular addition of allylsilanes to 3-vinylcycloalkenones provides a powerful means of constructing functionalized 5-5, 5-7, 6-5, and 6-7 bicyclic ring systems.Our results reveal a divergence in reactivity, dependent on reaction catalyst and substr
Majetich, George,Defauw, Jean,Ringold, Clay
p. 50 - 68
(2007/10/02)
REGIOSELECTIVITY IN INTRAMOLECULAR ADDITION OF ALLYLSILANES TO CONJUGAT DIENONES
The intramolecular addition of allylsilanes to conjugated dienones shows a divergence of regioselectivity as a function of reagent and substrate structure.The creation of 5-5, 6-5, 5-7, and 6-7 bicyclic ring systems is reported.
Majetich,G,Hull,K,Defauw,J,Desmond,R
p. 2747 - 2750
(2007/10/02)
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