- Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTF's) as redox active ligands
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A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF-DME) is reported. The tetrathifulvalene dimethylester (TTF-DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of t
- Sarhan, Abd El-Wareth A. O.,Murakami, Makoto,Izumi, Taeko
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p. 691 - 694
(2007/10/03)
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- INSERTION OF 1,3-DITHIOLIUM CARBENES INTO N-H BOND OF AMIDES AND IMIDES
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It was found that 1,3-dithiolium carbenes (4a-d) generated from 2-methoxy-1,3-dithioles (1a-d) were inserted into N-H bond of N-methylbenzamide, acetanilide and succinimide to form N-(1,3-dithiol-2-yl)amides (imides) 8-10, respectively.It was shown that N
- Buza, Daniela,Gradowska, Wanda
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p. 1059 - 1069
(2007/10/02)
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- Tetrathiafulvalenes. XXI Syntheses of Tetrathiafulvalenes from 2-Alkylthio-, 2-Arylthio- and 2-Alkylseleno-1,3-dithiolium Salts
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In the reaction of 2-alkylthio-, 2-arylthio- or 2-alkylseleno-1,3-dithiolium salts with trivalent phosphorus compounds in acetonitril tetrathiafulvalenes 2 are formed.As an intermediate we suppose a phosphorane, which reacts with further 1,3-dithiolium sa
- Fanghaenel, E.,Richter, A. M.,Schukat, G.
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p. 479 - 484
(2007/10/02)
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- CLEAVAGE OF 2-METHOXY-1,3-DITHIOLES BY ACIDS
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The reaction of 2-methoxy-1,3-dithioles (1) with acids, yielding 1,3-dithiolium salts (2) or 2,2'-bi(1,3-dithiolylidenes) (3) or both, was studied.It was found that the direction of this reaction was determined by the strength and the proportion of the ac
- Buza, Daniela,Gradowska, Wanda
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p. 775 - 782
(2007/10/02)
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- REACTIONS OF 1,3-DITHIOLIUM CARBENES IN SITU WITH AROMATIC ALDEHYDES
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It was found that 1,3-dithiolium carbenes (3) generated from various 1,3-dithiole derivatives reacted with aromatic aldehydes to form 2-benzoyl-2,2'-(1',3'-dithiolyl)-1,3-dithioles (6).The proposed mechanism of reaction has been discussed.
- Buza, Daniela,Gradowska, Wanda
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p. 717 - 729
(2007/10/02)
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- Organic Metals: a New Synthetic Route to Tetrathiafulvalenes
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We report here a new synthetic route to tetrathiafulvalenes in asimple one-step synthesis from 2-thioxo-1,3-dithioles.
- Coustumer, Gerard Le,Mollier, Yves
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