Reaction of Olefins with Se-Phenyl (Selenothioperoxy)benzoate: A New Anti-Markownikoff Benzeneselenenylation
A novel free radical addition of Se-phenyl (selenothioperoxy)benzoate (1) to a variety of olefins is described.The addition of selenosulphide (1) to terminal olefins proceeds regiospecifically to give the anti-Markownikoff benzeneselenenylated adducts.The
ADDITION OF S-BENZOYL PHENYLSELENOSULFIDE TO OLEFINS: SELENOTHIOCARBOXYLATION
Heating of S-benzoyl phenylselenosulfide and olefins with AIBN afforded selenothiocarboxylated products generated by a free radical process with high regiospecificity but lack of stereoselectivity.
Toru, Takeshi,Seko, Takuya,Maekawa, Eturo
p. 3263 - 3266
(2007/10/02)
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