Formation of hetero-boroxines: Dynamic combinatorial libraries generated through trimerization of pairs of arylboronic acids
Condensation of pairs of arylboronic acids provided homo- and hetero-boroxines in solution as evidenced from NMR spectra, and those boroxines were detected in the gas phase by GC-MS spectrometry. Equilibrium constants for the formation of these boroxines in solution were obtained through integration of pertinent signals in the NMR spectra of the mixtures ofboronic acids.
Tokunaga, Yuji,Ueno, Hiroki,Shimomura, Youji
p. 219 - 223
(2008/09/17)
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