101859-19-2

Basic information

• Product Name: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol
• CAS NO: 101859-19-2
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.2493
• Mol File: 101859-19-2.mol

Chemical Properties

• Boiling Point: 225.9°C at 760 mmHg
• Flash Point: 90.8°C
• Density: 0.913g/cm³
• Vapor Pressure: 0.0167mmHg at 25°C
• Refractive Index: 1.473
• CAS DataBase Reference: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(101859-19-2)
• EPA Substance Registry System: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(101859-19-2)

Safety Data

• Hazardous Substances Data: 101859-19-2(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 286-20-4 cyclohexane-1,2-epoxide 
• 936-67-4 2-(2-methyl-2-propenyl)cyclohexanone 
• 563-47-3 3-Chloro-2-methylpropene 
• 5674-01-1 2-methylallylmagnesium chloride 
• 286-20-4 cyclohexene oxide 
• 67883-62-9 2-methylallyltributyltin 

Downstream Products

• 101859-20-5 tert-Butyl-dimethyl-[(1R,2S)-2-(2-methyl-allyl)-cyclohexyloxy]-silane 
• 101859-25-0 (1S,2R)-2-((E)-2-Methyl-but-2-enyl)-cyclohexanol 
• 101859-21-6 1-((1R*,2S*)-2-((tert-butyldimethylsilyl)oxy)cyclohexyl)-2-propanone 
• 101859-24-9 tert-Butyl-dimethyl-[(1R,2S)-2-((E)-2-methyl-but-2-enyl)-cyclohexyloxy]-silane 
• 101859-23-8 (Z)-4-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-3-methyl-but-2-en-1-ol 
• 101859-23-8 (E)-4-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-3-methyl-but-2-en-1-ol 

Relevant articles and documents

Generation of allylic manganates from trimethylmanganate and allylic stannanes and their reactions with epoxides

A new method for forming allyldimethylmanganate has been developed. The preparation eliminated the need for prior generation of an allylmetal species such as allyllithium or allylmagnesium compounds. The reagents reacted with epoxides to give allylated products exclusively in good yields.

Preparation of Higher Order Cyano and "Non-Ate" Allyl Copper Reagents from the Reaction of Allyl Chlorides with a Formal Copper Anion

The generation of higher order and "non-ate" allyl organocopper reagents have been achieved through the low temperature reaction of allyl chlorides with a formal copper anion.The copper anion is generated via the low temperature reduction of Cu(I) complexes by two equivalents of lithium naphthalenide and then oxidatively adds to allyl chlorides with minimal homocoupling.These allyl organocopper reagents undergo substitution reactions with alkyl chlorides and epoxides as well as 1,4-conjugate addition reactions in good to excellent yields.