Methyl 2,3-Dideoxy-3-nitro-D-erythro-pentofuranoside, Isomers and Derivatives
Practical syntheses are described for the versatile intermediates, methyl 2,3-dideoxy-3-nitro-D-erythro-pentofuranoside (12), the corresponding uronic acid (2), and some derivatives, starting from either D-glucose or D-xylose.
Weber, J. F.,Talhouk, J. W.,Nachman, R. J.,You, Tian-Pa,Halaska, R. C.,et al.
p. 2702 - 2706
(2007/10/02)
A CHIRAL NITRONATE DIANION FROM D-GLYCERALDEHYDE. ENANTIOSPECIFIC SYNTHESIS OF 2,3-DIDEOXY-3-NITRO FURANOSIDES AND PYRANOSIDES
A new enantiospecific protocol for the synthesis of 2,3-dideoxy-3-nitro and 3-amino sugars is reported.Chiral nitronate dianione 3, derived from (+)-D-glyceraldehyde, is allylated and the resulting adduct 7 is transformed to either the methyl furanoside 9
Williams, Theresa M.,Mosher, Harry S.
p. 6269 - 6272
(2007/10/02)
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