Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
Main group element coordination polymers (MGE-CPs) are important compounds for the development of multifunctional materials. However, there has been a shortage of studies regarding their structural, optical, catalytic, mechanical, and antibacterial proper
Toward understanding the structure-catalyst activity relationship of new indium MOFs as catalysts for solvent-free ketone cyanosilylation
Four new indium metal-organic frameworks, MOFs, namely [In2(hfipbb)3(1,10-phen)2]·2H2O (InPF-12), [In2(hfipbb)3(2,2′-bipy)2]·2H2O (InPF-13), [In2(hfipbb)su
Aguirre-Daz, Lina Mara,Iglesias, Marta,Snejko, Natalia,Gutirrez-Puebla, Enrique,Monge, M. ngeles
p. 7058 - 7065
(2015/01/30)
Indium metal-organic frameworks as catalysts in solvent-free cyanosilylation reaction
Two new Indium MOFs with the bending multicarboxylate ligand H 2dpmda as a linker and different N-donor ancillary ligands were obtained; the two compounds are isoreticular with 2D-hcb uninodal 3-connected nets. Comparison of their activity in c
Aguirre-Diaz, Lina Maria,Iglesias, Marta,Snejko, Natalia,Gutierrez-Puebla, Enrique,Monge, M. Angeles
p. 9562 - 9571
(2013/11/19)
Cyanosilylation of carbonyl compounds with trimethylsilyl cyanide catalyzed by an yttrium-pillared silicotungstate dimer
An yttrium-pillared silicotungstate dimer (see picture) catalyzes the cyanosilylation of structurally diverse ketones and aldehydes with trimethylsilyl cyanide (TMSCN). The reactions proceed selectively and afford the corresponding cyanohydrin trimethylsi
Gold(III)-catalyzed cyanosilylation of ketones and aldehydes
Gold(III) chloride was found to be a highly efficient catalyst for the cyanosilylation of various ketones and aldehydes. The reactions were complete within 30 minutes at room temperature in the presence of only one mol% gold(III) chloride, yielding the co