102622-20-8

Basic information

• Product Name: PARA-DODECYLCALIX(8)ARENE
• Synonyms: PARA-DODECYLCALIX(8)ARENE
• CAS NO: 102622-20-8
• Molecular Formula: C152H240 O8
• Molecular Weight: 2195.53
• Mol File: 102622-20-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: PARA-DODECYLCALIX(8)ARENE(CAS DataBase Reference)
• NIST Chemistry Reference: PARA-DODECYLCALIX(8)ARENE(102622-20-8)
• EPA Substance Registry System: PARA-DODECYLCALIX(8)ARENE(102622-20-8)

Safety Data

• Hazardous Substances Data: 102622-20-8(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 104-43-8 4-dodecylphenol 
• 133708-89-1 para-dodecanoyl-calix[8]arene 

Relevant articles and documents

PREPARATION OF SERIES OF CALIX(6)ARENES AND CALIX(8)ARENES DERIVED FROM P-N-ALKYKPHENOLS.

The preparation of series of p-n-alkylcalix(6)arenes and p-n-alkylcalix(8)arenes by p-n-alkylphenol-formaldehyde condensations in basic conditions is described.

METAL COMPOUNDS OF CALIXARENES, DETERGENT COMPOSITIONS CONTAINING THEM AND USE THEREOF IN LUBRICANT COMPOSITIONS

The present invention relates to a metal compound of calixarene not containing sulfur and dispersible in oil, which can be partially salified, or neutral, or basic or overbased, said calixarene having general formula (I) in which: a) R1, R2, R3 and R4 are independently selected from hydrogen, or a group containing carbon and hydrogen, or a group containing in addition to carbon and hydrogen also heteroatoms, provided that said heteroatoms are not sulfur; b) one of the two substituents R5 and R6 is hydrogen, while the other may be selected from hydrogen, or a linear or branched alkyl with a number of carbon atoms between 1 and 6, preferably methyl, ethyl, 1-propyl, 2-propyl, n-butyl, sec-butyl, more preferably methyl or ethyl; c) n is the number of units of the calixarene ring and is comprised in the range between 4 and 16, preferably between 5 and 12; said calixarene being characterized in that in at least one of the n units of the calixarene ring, at least one of the substituents R1, R2, R3 and R4 contains at least one acid group of carboxylic type available for the reaction with a metal base, with the proviso that said acid group of carboxylic type is not contained in a unit of the calixarene ring derived from salicylic acid.

New Syntheses and Physical Properties of p-Alkylcalixarenes

Calixarenes (n=4, 6, and 8) bearing long p-alkyl groups (R=hexyl or dodecyl) have been synthesized by "direct" acylation of the p-position followed by silane reduction.The method is convenient and the yields are higher than those reported so far.Among them, p-hexanoylcalixarene showed a curious phase transition behavior; with raising the temperature it changed as crystal A -> liquid -> crystal B -> liquid.It was found on the basis of the solid 13C NMR spectra that this behavior is ascribed to a conformational change from "cone" (crystal A) to "partial cone" (crystal B).