Activation of Carbon Dioxide: Nickel-Catalyzed Electrochemical Carboxylation if Diynes
The simualtaneous activation of carbon dioxide and diynes by electrogenerated LNi(0) complexes (L=bpy, pentamethyldiethylenetriamine: PMDTA) enables the selective incorporation of one molecule of CO2 into the unsaturated systems and the preparative-scale
Derien, Sylvie,Clinet, Jean-Claude,Dunach, Elisabet,Perichon, Jacques