- Manipulating the enone moiety of levoglucosenone: 1,3-Transposition reactions including ones leading to isolevoglucosenone
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The manipulation of the enone moiety associated with the biomass-derived, homochiral and now abundant compound levoglucosenone (1) is described. While the trichloroacetimidates derived from the allylic alcohols 3 and 4 failed to engage in Overman-type rea
- Ma, Xinghua,Liu, Xin,Yates, Patrick,Raverty, Warwick,Banwell, Martin G.,Ma, Chenxi,Willis, Anthony C.,Carr, Paul D.
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p. 5000 - 5011
(2018/06/20)
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- SYNTHESIS AND THERMAL CHEMISTRY OF ISOLEVOGLUCOSENONE
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Isolevoglucosenone (1,6-anhydro-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose, 3) has been synthesized from levoglucosenone (2) in six steps.Thus, 1,6-anhydro-4-O-benzyl-3-deoxy-β-D-erythro-hexopyranos-2-ulose, obtained by Michael addition of benzyl al
- Furneaux, Richard H.,Gainsford, Graeme J.,Shafizadeh, Fred,Stevenson, Thomas T.
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p. 113 - 128
(2007/10/02)
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