ASYMMETRIC RING-OPENING OF CYCLOHEXENE OXIDE WITH VARIOUS THIOLS CATALYZED BY ZINC Lg-TARTRATE
Optically active trans-2-(arylthio or alkylthio)-cyclohexanols are prepared by the asymmetric ring-opening of cyclohexene oxide with various arylthiols or alkylthiols in 52-85 percent ee by the use of zinc Lg-tartrate as a heterogeneous chiral Lewis acid catalyst.
Yamashita, Hiroyuki,Mukaiyama, Teruaki
p. 1643 - 1646
(2007/10/02)
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