1029612-18-7Relevant articles and documents
Stereoselective total syntheses of insect juvenile hormones JH 0 and JH i
Manabe, Atsushi,Ohfune, Yasufumi,Shinada, Tetsuro
experimental part, p. 1213 - 1216 (2012/07/03)
Total syntheses of juvenile hormones JH 0 and JH I have been achieved by a new iterative enol tosylate homologation strategy. Georg Thieme Verlag Stuttgart · New York.
Mild, efficient, and robust method for stereocomplementary iron-catalyzed cross-coupling using (E)- and (Z)-enol tosylates
Nishikado, Hiroshi,Nakatsuji, Hidefumi,Ueno, Kanako,Nagase, Ryohei,Tanabe, Yoo
scheme or table, p. 2087 - 2092 (2010/10/03)
Iron-catalyzed cross-coupling of Grignard reagents (RMgX) with (E)- and (Z)-enol tosylates proceeded smoothly to give a variety of the corresponding (E)- and (Z)-trisubstituted ,-unsaturated methyl esters (total 30 examples; 55-98% yield). The simple, mild, stereoretentive method utilized iron(III) chloride (FeCl3), iron(III) acetylacetonate [Fe(acac)3], and iron(III) tris(dibenzylmethane) [Fe(dbm). The (E)- and (Z)-enol tosylates were readily prepared by the reported stereocomplementary tosylation method from methyl -keto esters or -formyl esters. Methyl -formyl esters were obtained via a practical and robust TiCl4-Et3N-mediated -formylation of methyl esters with methyl formate.
General, robust, and stereocomplementary preparation of β-ketoester enol tosylates as cross-coupling partners utilizing TsCl-N-methylimidazole agents
Nakatsuji, Hidefumi,Ueno, Kanako,Misaki, Tomonori,Tanabe, Yoo
supporting information; body text, p. 2131 - 2134 (2009/05/26)
(Chemical Equation Presented) We have developed a general, robust, and cost-effective method for the (E)- or (Z)-stereocomplementary enol tosylation of β-ketoesters using TsCl-N-methylimidazole (NMI)-Et3N or LiOH. TsCl coupled with NMI formed a
(Z)‐enol p‐tosylate derived from methyl acetoacetate: A useful cross‐coupling partner for the synthesis of methyl (Z)‐3‐phenyl (or aryl)‐2‐butenoate
Ashida, Yuichiro,Nakatsuji, Hidefumi,Tanabe, Yoo
, (2018/11/25)
Procedures yielding (Z)‐3‐(p‐toluenesulfonyloxy)but‐2‐enoate [(Z)‐1] as white prisms and methyl (Z)‐3‐phenyl‐2‐butenoate [(Z)‐2] as a colorless oil are presented. Following are notes on the instruments and chemicals used and required. The chapter conclude