- Hydrosilylation of 1,4-Bis(trimethylsilyl)butadiyne and Silyl-Substituted Butenynes
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Hydrosilylation of 1,4-bis(trimethylsilyl)butadiyne using various hydridosilanes and Pt(IV), Pt(0), Rh(I) or Pd catalyst gave, depending on catalyst and hydridosilane, 1,1,3,4-tetrasilyl-substituted 1,3-butadienes or 1,1,3,4-tetrasilyl-substituted 1,2-but
- Kusumoto, Tetsuo,Ando, Kenji,Hiyama, Tamejiro
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p. 1280 - 1290
(2007/10/02)
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- HYDROSILYLATION OF 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
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Hydrosilylation of 1,4-bis(trimethylsilyl)-1,3-butadiyne with platinum and rhodium catalyst proceeded stepwise to give first 2-silyl-1,4-bis(trimethylsilyl)-1-buten-3-ynes and then 1,3-disilyl-1,4-bis(trimethylsilyl)-1,2-butadienes in high yields.
- Kusumoto, Tetsuo,Hiyama, Tamejiro
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p. 1405 - 1408
(2007/10/02)
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