Syntheses of phosphatidyl-β-d-glucoside analogues to probe antigen selectivity of monoclonal antibody 'DIM21'
Herein, we report the chemical syntheses of a series of phosphatidyl-β-d-glucoside (PtdGlc) analogues, including 6-O-Ac, sn-2-O-Me, phosphorothioate as well as phosphatidylgalactoside and -mannoside derivatives. In the key step, β-glycosyl H-phosphonate w
First synthesis of natural phosphatidyl-β-d-glucoside
Herein, we report the chemical synthesis of naturally occurring mammalian phosphatidyl-β-d-glucoside (PtdGlc), in order to confirm the proposed structure and to clarify its stereochemistry. We designed a convergent synthetic strategy, suitable to prepare
Greimel, Peter,Ito, Yukishige
p. 3562 - 3566
(2008/09/19)
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