Activation of C-H Bonds of Heterocyclic and Alicyclic Compounds Using Calcium Atom
Calcium atoms have been inserted into C-H bonds of heterocyclic (furans and thiophene) and alicyclic compounds (cyclohexanes and cyclopentane) to give the corresponding organocalcium hydrides.The organocalcium hydrides thus produced reacted with trimethylchlorosilane to give trimethylsilyl-substituted heterocyclic and alicyclic compounds, and a reduced product (trimethylsilane).
Mochida, Kunio,Kojima, Kenji,Yoshida, Yasuhiro
p. 2255 - 2256
(2007/10/02)
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