Metal-free radical-mediated C(sp3)-H heteroarylation of alkanes
Herein we disclose a metal-free, N/O-centered radical-promoted Minisci reaction, in which the coupling of various heteroarenes with simple alkanes proceeds under mild conditions. The reaction conditions are neutral; no extra acid is added to preactivate N
Eco-friendly atom-economical synthesis of 2-substituted-benzo[d]thiazoles and 2-substituted-benzo[d]oxazoles using 2-acylpyridazin-3(2H)-ones
Efficient and green syntheses of heterocycles are of great importance. In this work, we have demonstrated the synthesis of benzo[d]thiazoles and benzo[d]oxazoles using 2-acylpyridazin-3(2H)-ones as acyl transfer agents under transition-metal-free and eco-
Sung, Gi Hyeon,Lee, In-Hye,Kim, Bo Ram,Shin, Dong-Soo,Kim, Jeum-Jong,Lee, Sang-Gyeong,Yoon, Yong-Jin
p. 3530 - 3535
(2013/05/08)
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