Synthesis of trifluoromethanesulfinamidines and -sulfanylamides
(Chemical Equation Presented) Fluorinated moieties constitute important substituents used in many applications to modify the properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable intermediate that can then react with various primary amines to give trifluoromethanesulfinamidines and trifluoromethane-sulfanylamides. Such compounds were unknown until now and constitute interesting new families of fluorinated molecules.
Ferry, Aurelien,Billard, Thierry,Langlois, Bernard R.,Bacque, Eric
supporting information; experimental part
p. 9362 - 9365
(2009/04/11)
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