LiCl-mediated preparation of functionalized benzylic indium(III) halides and highly chemoselective palladium-catalyzed cross-coupling in a protic cosolvent
(Chemical Equation Presented) Sensitive functional groups such as COR, CHO, or CH2OH can be present in benzylic indium reagents prepared by the direct insertion of indium in the presence of LiCl. These reagents undergo palladium-catalyzed cross
Chen, Yi-Hung,Sun, Mai,Knochel, Paul
supporting information; experimental part
p. 2236 - 2239
(2009/08/14)
Nickel-catalyzed cross-coupling reactions of benzylic zinc reagents with aromatic bromides, chlorides and tosylates
Benzylic zinc reagents prepared by direct insertion of zinc to benzylic chlorides in the presence of LiCl undergo smooth cross-coupling reactions with aromatic chlorides, bromides and tosylates using Ni(acac)2 and PPh3 as a catalyst
Schade, Matthias A.,Metzger, Albrecht,Hug, Stephan,Knochel, Paul
supporting information; experimental part
p. 3046 - 3048
(2009/02/04)
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