Carboxylative Coupling of Propargylic Alcohols with Allyl Chloride
Palladium-mediated reaction of lithium 2-alkynyl carbonates with allyl chloride affords cyclic carbonates whose alkaline hydrolysis gives keto alcohols in good yields.The combination of the above procedure with the formation of lithium 2-alkynolates from
Iritani, Koji,Yanagihara, Naoto,Utimoto, Kiitiro
p. 5499 - 5501
(2007/10/02)
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