- Effets de la stabilisation captodative XX. Addition des radicaux nucleophiles derives d'alcanes, d'ethers, de thioethers, d'amides, d'amines, d'alcools, d'acetals ou de thioacetals a l'α-tert-butyl-thioacrylonitrile
-
Oxidation of alkanes, ethers, thiothers, amides, amines, alcohols, ketals and thioketals in the presence of the radicophilic olefin α-tert-butylthioacrylonitrile 3a with capto-dative (cd) substitution does not give the usual radical decay products.Except for strongly stabilised radicals, all others formed by oxidation are trapped by 3a to give bridged dehydrodimers 5 in good yields.
- Mignani, S.,Janousek, Z.,Merenyi, R.,Viehe, H. G.
-
p. 1267 - 1274
(2007/10/02)
-