Understanding the reactivity of enol ether radical cations: Investigation of anodic four-membered carbon ring formation
The reactivity of enol ether radical cations was investigated in anodic four-membered carbon ring formations, advancing the mechanistic understanding of these reactions. The mono-ring-containing aromatic cations were reduced through inter- or intramolecular electron transfer to give mono- or bis-ring-containing compounds, respectively. Small structural changes in the hydrocarbon linkers tethering two aromatic rings exerted a powerful effect on the efficiency of such electron transfer events.
Yamaguchi, Yusuke,Okada, Yohei,Chiba, Kazuhiro
p. 2626 - 2638
(2013/04/23)
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