106018-81-9Relevant articles and documents
Scandium(III) Triflate-Catalyzed anti-Markovnikov Hydrothiolation of Functionalized Olefins
Kuciski, Krzysztof,Pawluc, Piotr,Hreczycho, Grzegorz
supporting information, p. 3936 - 3942 (2016/01/25)
Scandium(III) triflate promoted highly selective addition of thiols to functionalized olefins under mild conditions. The addition follows anti-Markovnikov regioselectivities, which are unusual for Lewis acids-catalyzed hydrothiolation. This reaction marks broad functional groups tolerance, which opens a beneficial synthetic route to functionalized and biologically active thio-compounds. This method is broadly applicable and offers a simple work-up in the green manner.
One-Flask Synthesis of Sulfides from Alcohols and Alkyl Halides Using Benzoxazoline-2-thione
Takeuchi, Yasuo,Sakagawa, Keiko,Kubo, Masumi,Yamato, Masatoshi
, p. 1323 - 1327 (2007/10/02)
The synthesis of sulfides from alcohols and benzoxazoline-2-thione (I) was studied to establish its generality and the mechanism of the reaction.A one-flask synthesis of sulfides from alcohols was developed.According to this procedure, various sulfides were prepared without the use of illsmelling thiols.Moreover, partial sulfenylation of diols to give sulfenyl alcohols was achieved.Keywords - one-flask synthesis; benzoxazoline-2-thione; partial sulfenylation; sulfide; sulfenyl alcohol