SYNTHESIS OF 2- AND 4-NITROPYRIMIDINES AND 2-NITRO-sym-TRIAZINES BY OZONIZATION OF HYDROXYAMINO AND NITROSO DERIVATIVES
The action of ozone on aryl(methyl)-substituted 2- and 4-hydroxyamino- or -nitrosopyrimidines in chloroform gave 2- and 4-nitropyrimidines.The unambiguous character of the process depends on the molar ratio of the substrate and ozone; the side formation o
Moskalenko, G. G.,Sedova, V. F.,Akhmetova, V. R.,Odinokov, V. N.,Mamaev, V. P.
p. 557 - 560
(2007/10/02)
OXIDATION OF HYDROXYAMINO- AND NITROSOPYRIMIDINES. SYNTHESIS OF 2- AND 4-NITROPYRIMIDINES
Oxidation of phenyl- and methyl-substituted 2- and 4-hydroxyamino- and -nitrosopyrimidines has given the azoxy- and nitropyrimidines, respectively.The behavior of the nitropyrimidines obtained towards reduction and nucleophilic substitution is considered.
Moskalenko, G. G.,Sedova, V. F.,Mamaev, V. P.
p. 919 - 924
(2007/10/02)
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