106867-97-4

Basic information

• Product Name: 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE
• Synonyms: 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE;1,1'-(P-XYLYLENE)BIS(4,4'-BIPYRIDINIUM) DIBROMIDE;1,1''-(1,4-Phenylenebis(methylene))bis(([4,4'-bipyridin]-1-ium)) bromide
• CAS NO: 106867-97-4
• Molecular Formula: 2Br*C₂₈H₂₄N₄
• Molecular Weight: 576.32
• Product Categories: Pyridinium Compounds
• Mol File: 106867-97-4.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE(106867-97-4)
• EPA Substance Registry System: 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE(106867-97-4)

Safety Data

• Hazardous Substances Data: 106867-97-4(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE is used as a reactant in the synthesis of novel 1D Pb(II) halide supramolecular polymers. Its unique structure allows for the formation of these polymers, which have potential applications in various fields.
Used in Supramolecular Chemistry:
In the field of supramolecular chemistry, 1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE is used as a building block for the creation of complex molecular structures. Its ability to form supramolecular polymers makes it a valuable component in the development of new materials with unique properties.
Used in Material Science:
1,1'-[1,4-PHENYLENEBIS(METHYLENE)]BIS(4,4'-BIPYRIDINIUM) DIBROMIDE plays a crucial role in material science, particularly in the development of new materials with specific properties. The supramolecular polymers synthesized using this compound can be tailored for various applications, such as sensors, catalysts, or advanced materials with unique mechanical or electronic properties.

Upstream product

• 1643-19-2 tetrabutylammomium bromide 
• 623-24-5 1,4-bis(bromomethyl)benzene 
• 553-26-4 4,4'-bipyridine 

Downstream Products

• 108861-39-8 1,1''-[1,4-phenylenebis(methylene)]bis[1'-(phenylmethyl)-4,4'-bipyridinium] tetrabromide 
• 108861-27-4 1'1'''-dibenzyl-1,1''-1,4-phenylene-bis(methylene)bis-4,4'-bipyridinetetraium-tetrakis(hexafluorophosphate) 
• 108861-20-7 1,1-[1,4-phenylenebis(methylene)]bis-4,4'-pyridylpiridinium bis(hexafluorophosphate) 

Relevant articles and documents

An Organic Receptor Isolated in an Unusual Intermediate Conformation: Computation, Crystallography, and Hirshfeld Surface Analysis

1,1″-1,4-Phenylene-bis(methylene)bis-4,4′-bipyridinium cation [C28H24N4]2+ (c), an organic receptor that generally crystallizes in its anti conformation, has recently been shown to be isolated in its syn conform

Self-assembly of cyclobis(paraquat-p-phenylene)s

Cyclobis(paraquat-p-phenylene)s complexed with anionic surfactants exhibit liquid-crystalline states and form pseudorotaxanes with tetrathiafulvalene in the condensed states.

Binding behaviors of p-sulfonatocalix[4]arene with gemini guests

A dozen of homoditopic cations, possessing different spacer lengths and rigidities, as well as sizes, shapes, and charges of terminal groups, were synthesized as candidate gemini guests for the complexation of p-sulfonatocalix[4]arenes (SC4A). The 12 gemini guests are divided into five species according to the different terminal groups: imidazolium (G1-G3), pyridinium (G4-G6), quinolinium (G7), viologen (G8-G11), and 1,4-diazabicyclo[2.2.2]octane (DBO, G12). Their binding structures and stoichiometries with SC4A were examined by NMR spectroscopy, which is helpful to construct diverse highly ordered assemblies. The obtained results show that the length of the linkers, as well as the charge numbers on the end groups have a pronounced effect on the binding stoichiometry, whereas the size and shape of the terminal groups have no significant influence. Furthermore, both the stability constants and thermodynamic parameters of SC4A with the terminal subunits were determined by the isothermal titration calorimetry experiments, which are valuable to understand the binding behavior, giving quantitatively deep insight.

Syntheses and characterization of two novel 1D Pb(II) Halide supramolecular polymers possessing incomplete Cubane subunit directed by π-conjugated Dication templates

Two novel cation-templated complexes, {(1, 4-PMBP)[Pb4I10] DMF}n(1) {(DBBP)2[Pb5I8Br6]}n(2), (1, 4-PMBP 2Br =1, 1"-[1, 4-phenylene-bis(methylene)]bis-4, 4'-bipyridiniu

Mechanical motion in the solid state and molecular recognition: Reversible cis-trans transformation of an organic receptor in a solid-liquid crystalline state reaction triggered by anion exchange

An organic receptor [C28H24N4]2+ can be obtained with its unusual cis-form when it is ion-paired with a [Zn(dmit)2]2- coordination complex anion with the isolation of [C28H24N4][Zn(dmit)2]·2DMF (2). Compound 2 shows reversible cis-trans isomerization of the cationic receptor in a solid to solid transformation in a solid-liquid interface reaction.

ANALYTE DETECTION USING NEAR-INFRARED FLUOROPHORES

Embodiments of compounds for selectively detecting an analyte are disclosed, along with methods and kits for detecting analytes with the compounds. The compounds are bridged viologen conjugates including at least one fluorophore according to the general structure At least one of R1/R2, R2/R3, R3/R4, R5/R6, R6/R7, and/or R7/R8 together form a substituted or unsubstituted cycloalkyl or aryl.

Catenane and inclusion complex as photochromic compounds involving viologen units

Catenane (1) consisting of a tetracationic cyclophane (2) and p-benzocrown ether (5) has been prepared to investigate its photochromic behavior in a poly(N-vinyl-2-pyrroridone) (PVP) film by comparing with that of 2 in the absence and the presence of π-el

THIOL DETECTION

Embodiments of compounds for selectively detecting a thiol are disclosed. In some embodiments, the compounds are bridged viologens, and the compounds are capable of reacting with homocysteine and/or glutathione in a buffered solution to produce a change i

SINGLE AND DOUBLE BRIDGED VIOLOGENES AND INTRAMOLECULAR PIMERIZATION OF THEIR CATION RADICALS

As an extension of our studies dealing with reversible redox systems, six tetraquaternary salts have been synthetized.These compounds contain two 4,4'-bipyridinium units which are connected by either one or two rigid bridges.The single bridged systems (o-