- DOUBLE ESTERS AND LUBRICANTS THEREOF
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A new compound that comprises a branched ester based primarily on renewable resources preferably has good friction properties, a low pour point; acceptable viscosity, and good thermal oxidative stability and is useful as a functional fluid such as a lubricant. The branched ester is a double ester of a polyhydric alcohol having at least two active hydrogen groups separated by at least one carbon atom, wherein each hydroxyl group of the polyhydric alcohol is esterified with one monobasic secondary hydroxy fatty acid group and each hydroxyl of a fatty acid is esterified with one alkyl or cycloalkyl monobasic carboxylic acid group that has from 2 to 22 carbon atoms.
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Page/Page column 4
(2012/03/08)
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- ACTIVATION AND SYNTHETIC APPLICATION OF THIOSTANNANES. PROTECTION OF CARBOXYL GROUPS WITH α-METHYLCINNAMYL ALCOHOL AS A MEANS OF CHEMODIFFERENTIATION AND SELECTIVE ACTIVATION
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α-Methylcinnamyl (MEC) esters are converted into parent carboxylic acids under mild conditions, various functions being tolerated including acetoxy, siloxy, MEM, and so on.Furthermore, MEC esters are transformed into other esters through CsF-promoted alkylation of intermediary organotin carboxylates.
- Sato, Tsueno,Otera, Junzo,Nozaki, Hitoshi
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p. 2959 - 2962
(2007/10/02)
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