cas 107073-27-8, [3-(1H-PYRROL-1-YL)-2-THIENYL]METHANOL | Articles data ｜lookchem

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107073-27-8

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Metal-Free Aerobic Oxidative Selective C-C Bond Cleavage in Heteroaryl-Containing Primary and Secondary Alcohols
A transition-metal-free aerobic oxidative selective C-C bond-cleavage reaction in primary and secondary heteroaryl alcohols is reported. This reaction was highly efficient and tolerated various heteroaryl alcohols, generating a carboxylic acid derivative and a neutral heteroaromatic compound. Experimental studies combined with density functional theory calculations revealed the mechanism underlying the selective C-C bond cleavage. This strategy also provides an alternative simple approach to carboxylation reaction.
Xia, Anjie,Qi, Xueyu,Mao, Xin,Wu, Xiaoai,Yang, Xin,Zhang, Rong,Xiang, Zhiyu,Lian, Zhong,Chen, Yingchun,Yang, Shengyong
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(2019/05/07)

PYRROLOTHIENOPYRIMIDINES II. SYNTHESIS OF 4-AMINOPYRROLOTHIENO (AND ) PYRIMIDINES
Cyclization of the appropriate cyanothienylpyrrolylcarboxylic acid azides in boiling ortho-dichlorobenzene conducted to the corresponding aminopyrrolothienopyrimidines.
Rault, Sylvain,Effi, Yamien,Lancelot, Jean-Charles,Robba, Max
p. 575 - 578
(2007/10/02)

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107073-28-9
3-(1H-pyrrol-1-yl)-2-thiophenecarbaldehyde

Chemical Properties

Melting Point: 100 °C (sublm)(Press: 5 Torr)
Boiling Point: 344.1 °C at 760 mmHg
Flash Point:161.9 °C
Density: 1.25 g/cm³
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Vapor Pressure: 2.58E-05mmHg at 25°C
Refractive Index: 1.64
PKA: 13.08±0.10(Predicted)
Sensitive: Air Sensitive
PSA: 53.40000
LogP: 2.03110

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