Intramolecular anodic olefin coupling reactions and the synthesis of cyclic amines
Anodic olefin coupling reactions using a tosylamine trapping group have been studied. The cyclizations are favored by the use of a less-polar radical cation and more basic reaction conditions. The most significant factor for obtaining good yields of cyclic product is the use of the more basic reaction conditions. However, a number of factors including the nature of both the solvent and the electrolyte used can influence the yield of the cyclizations. The cyclizations allow for the rapid synthesis of both substituted proline and pipecolic acid type derivatives.
Xu, Hai-Chao,Moeller, Kevin D.
supporting information; experimental part
p. 2839 - 2844
(2010/06/11)
Intramolecular anodic olefin coupling reactions: The use of a nitrogen trapping group
Anodic olefin coupling reactions using a tosylamine trapping group have been studied. The cyclizations are favored by the use of a less-polar radical cation and more basic reaction conditions. The most significant factor for obtaining good yields of cyclic product is the use of the more basic reaction conditions. The cyclizations allow for the rapid synthesis of substituted proline derivatives. Copyright
Xu, Hai-Chao,Moeller, Kevin D.
supporting information; experimental part
p. 13542 - 13543
(2009/02/06)
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