REACTION OF PUMMERER REARRANGEMENT INTERMEDIATE WITH AROMATIC COMPOUNDS: A NOVEL SYNTHESIS OF 1-(SUBSTITUTED-ARYL)METHYLTHIOMETHANEPHOSPHONATES
Pummerer reaction intermediate(2) of methylsulfinylmethanephosphonate(1) has been found to react mildly with aromatic compounds in the presence of tin(IV) chloride to afford 1-(substituted-aryl)methylthiomethanephosphonates.
Kim, Taek Hyeon,Kim, Dae Young,Oh, Dong Young
p. 755 - 760
(2007/10/02)
SYNTHESIS OF 1-(SUBSTITUTED-ARYL) METHYLTHIOMETHANEPHOSPHONATES BY FRIEDEL-CRAFTS REACTION OF AROMATIC COMPOUNDS WITH CHLORO(METHYLTHIO)METHANEPHOSPHONATE
Friedel-Crafts reaction of aromatic compounds with chloro(methylthio)methanephosphonate(1) under mild condition in the presence of Lewis acid affords 1-(substituted-aryl)methylthiomethanephosphonates(2).
Kim, Taek Hyeon,Oh, Dong Young
p. 1165 - 1166
(2007/10/02)
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