Enthalpy of solution of hexaglyme in mixtures of water with N,N-dimethylformamide at 298.15 K
The enthalpies of solution of hexaglyme in water-N,N-dimethylforamide mixtures have been measured at 298.15 K. To analyze the process of hydrophobic hydration the cage model proposed by Mastroianni, Pical and Lindenbaum was used. The enthalpic effect of h
AFFINITIES OF CROWN ETHERS, GLYMES, AND POLYAMINES FOR ALKALI PICRATES IN TOLUENE. APPLICATION OF POLYMER-SUPPORTED LINEAR POLYETHERS.
This work reports the measurements of K values for polyamines, glymes, a few glycols (including that of a long-chain polyethylene glycol, carbowax 6000), and some frequently used cation-binding ligands as complexers of lithium or sodium picrate in toluene as solvent. K values for different resins obtained with the same soluble ligand provide a comparison of the effectiveness of these resins in binding ionic solutes.
Xu,Smid
p. 3790 - 3796
(2007/10/02)
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