107794-42-3

Basic information

• Product Name: 3-phenoxybenzyl (1S,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate
• CAS NO: 107794-42-3
• Molecular Formula: C₂₂H₂₀ClF₃O₃
• Molecular Weight: 424.8406
• Mol File: 107794-42-3.mol

Chemical Properties

• Boiling Point: 454.4°C at 760 mmHg
• Flash Point: 142°C
• Density: 1.311g/cm³
• Vapor Pressure: 1.92E-08mmHg at 25°C
• Refractive Index: 1.567
• CAS DataBase Reference: 3-phenoxybenzyl (1S,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenoxybenzyl (1S,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate(107794-42-3)
• EPA Substance Registry System: 3-phenoxybenzyl (1S,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate(107794-42-3)

Safety Data

• Hazardous Substances Data: 107794-42-3(Hazardous Substances Data)

Upstream product

• 393870-46-7 3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropanecarbonyl chloride 
• 13826-35-2 3-Phenoxybenzyl alcohol 
• 84773-69-3 3-phenoxybenzyl (+/-)-cis,trans-3-formyl-2,2-dimethylcyclopropanecarboxylate 
• 26046-85-5 phenothrin 
• 107686-50-0 (3-phenoxyphenyl)methyl (1RS,3SR)-3-(1-acetoxy-2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethylcyclopropanecarboxylate 
• 107686-47-5 (3-phenoxyphenyl)methyl (1RS,3SR)-3-(2,2-dichloro-3,3,3-trifluoro-1-hydroxypropyl)-2,2-dimethylcyclopropanecarboxylate 

Relevant articles and documents

AGRICULTURAL CHEMICALS

The present invention relates to derivatives of compounds which are known to be of use in the field of agriculture. These derivatives are differentiated from the parent active compound by virtue of being redox derivatives of the active compound. This means that one or more of the functional groups in the active compound has been converted to another group in one or more changes one or more of which may be considered to represent a change of oxidation state relative to the groups in the original compound. We refer to these compounds generally as redox derivatives. The compounds are of use as insecticides, herbicides and insect repellents.

AGRICULTURAL CHEMICALS

The present invention relates to derivatives of compounds which are known to be of use in the field of agriculture. These derivatives are differentiated from the parent active compound by virtue of being redox derivatives of the active compound. This means that one or more of the functional groups in the active compound has been converted to another group in one or more changes one or more of which may be considered to represent a change of oxidation state relative to the groups in the original compound. We refer to these compounds generally as redox derivatives. The compounds are of use as insecticides, herbicides and insect repellents.

2,2-Dimethylcyclopropane-carboxylic acid derivatives

A 2,2-dimethylcyclopropanecarboxylic acid derivative having the formula: STR1 wherein R1 is an alkyl group or an aryl group, R2 is a hydrogen atom, an acyl group, a sulfonyl group or an alkyl group, and each of X1 and X2 is a halogen atom.

Insecticidal resin coating film

An insecticidal resin coating film comprising a combination of an acrylonitrile and/or methacrylonitrile copolymer resin and an insecticidal component selected from the group consisting of specified compounds exhibits an insecticidal effect, since the compound is kept on the surface of the coating film in a state capable of exhibiting its insecticidal effect for a long period of time.

PRACTICAL AND STEREOCONTROLLED SYNTHESES OF BOTH (1R*,3S*)- AND (1R*,3R*)-3-(2-CHLORO-3,3,3-TRIFLUORO-1-PROPENYL)-2,2-DIMETHYLCYCLOPROPANECARBOXYLATES

The title compounds of (1R*,3S*) configuration were prepared from 3-formyl-2,2-dimethylcyclopropanecarboxylate by addition of CF3CCl2ZnCl, acetylation, and reductive β-elimination with zinc, whereas the (1R*,3R*) isomer was derived from Me2C=CHCH(OH)CCl2CF3 by diazoacetylation, Cu(II) catalyzed intramolecular cyclization, and the zinc reduction.

Insecticidal perhaloalkylvinylcyclopropanecarboxylates

Perhaloalkylvinylcyclopropanecarboxylates having the general formula STR1 are disclosed wherein one of Y and Z is a perhaloalkyl group. Compounds in which R is hydroxy, halogen or lower alkoxy are novel intermediates for preparation of insecticidal esters in which R is --OR1 where R1 is a wide variety of alcohol residues. The insecticidal efficacy and preparation of the compounds and intermediates therefor are described and exemplified.