108158-00-5Relevant articles and documents
Synthesis of aryl sulfonyl fluorides from aryl sulfonyl chlorides using sulfuryl fluoride (SO2F2) as fluoride provider
He, Yunlu,Liu, Qiang,Pan, Xi,Peng, Sanwen,Qin, Hua-Li,Song, Xuyan,Tang, Haolin,Wang, Bo,Wei, Min
supporting information, (2022/02/02)
A highly efficient method for the synthesis of aryl sulfonyl fluorides was developed from aryl sulfonyl chlorides using SO2F2 as fluoride source in up to 98% isolated yield under mild conditions. Gram scale experiments were also conducted, revealing the good practicality of this new protocol.
Hetaryl Bromides Bearing the SO2F Group – Versatile Substrates for Palladium-Catalyzed C–C Coupling Reactions
Cherepakha, Artem Yu.,Stepannikova, Kateryna O.,Vashchenko, Bohdan V.,Gorichko, Marian V.,Tolmachev, Andrey A.,Grygorenko, Oleksandr O.
, p. 6682 - 6692 (2018/11/30)
Synthesis of novel five- and six-membered heteroaromatic sulfonyl fluorides bearing bromine atom at various positions of the heterocyclic ring is described. The synthetic utility of these compounds is demonstrated by the Suzuki, Stille, and Negishi cross-