108286-71-1Relevant articles and documents
Indium-catalyzed enantioselective allylation of aldehydes with β-carbonyl allylstannanes: An efficient synthetic method for chiral α-methylene-γ-lactones
Suzuki, Takamasa,Atsumi, Jun-ichi,Sengoku, Tetsuya,Takahashi, Masaki,Yoda, Hidemi
, p. 128 - 136 (2010/09/18)
The catalytic enantioselective allylation of aldehydes with β-carbonyl allyltributylstannanes in the presence of chiral indium complexes gave the optically active homoallylic alcohols, which can be converted to the corresponding optically active α-methyle
ORGANIC TELLURIUM COMPOUND, PROCESS FOR PRODUCING THE SAME, LIVING RADICAL POLYMERIZATION INITIATOR, PROCESS FOR PRODUCING POLYMER WITH THE SAME, AND POLYMER
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Page/Page column 9, (2010/02/11)
An organotellurium compound of the formula (1) is useful as a living radical polymerization initiator and makes possible precision control of molecular weights and molecular weight distributions under mild conditions wherein R1 is C1-C8 alkyl, R2 and R3 are each a hydrogen atom or C1-C8 alkyl, and R4 is aryl, substituted aryl, aromatic heterocyclic group, hydroxycarbonyl or cyano.
Radical Reactions in Synthesis: Carbon-Carbon Bond Formation from 2-Substituted Allyl Trialkyl Stannanes
Baldwin, Jack E.,Adlington, Robert M.,Birch, David J.,Crawford, James A.,Sweeney, Joseph B.
, p. 1339 - 1340 (2007/10/02)
A competing 1,3-rearrangement of allyl stannanes has been demonstrated to occur under the normal thermal homolytic allyl transfer reaction conditions which limits the substitution patterns in these processes; two methacrylyl stannanes are described which allow the transfer of the methacrylyl moiety to alkyl bromides and iodides under mild conditions.
