108292-99-5Relevant articles and documents
Regioselective and Stereoselective Oxirane Ring-Openings of 2,3-Anhydropentopyranosides with Some Methyl Group Donating Organometallic Reagents
Inghardt, Tord,Frejd, Torbjoern,Magnusson, Goeran
, p. 4542 - 4548 (2007/10/02)
By the proper choice of methyl group transferring reagents organometallic (Me4AlLi, Me4AlLi/MeLi (1:1), Me2CuLi, Me3Al, Me2Mg) it is possible to selectively introduce a methyl group into the 2- or 3-position via epoxide ring-opening of four easily availab
Efficient High-Yielding Syntheses and NMR Spectroscopic Studies of Some Fluorodeoxy Sugars
Latif, Farzana,Malik, Abdul,Voelter, Wolfgang
, p. 617 - 620 (2007/10/02)
Displacement of the triflyl group by fluoride ion in benzyl 2,3-anhydro-4-O-(trifluoromethylsulfonyl)pyranosides 1-3 leads with stereochemical inversion to the 4-fluoro-4-deoxy sugars 4-6, providing a general method for the introduction of fluorine in the