ASYMMETRIC INDUCTION IN THE ENE REACTION OF GLYOXYLATE ESTERS OF 8-PHENYLMENTHOL
We recently communicated (J.K.Whitesell, A.Bhattacharya, D.A.Aguilar and K.Henke, J.Chem.Soc.Chem.Commun. 989 (1982)) a highly efficient and effective method for the control of absolute stereochemistry through asymmetric induction in the ene reaction the chiral glyoxylate 1 with alkenes.We now have accumulated sufficient information on this process in terms of both its mechanistic details as well as its scope and applicability to a variety of situations that warrants a more complete presentation of these reactions.
Whitesell, James K.,Bhattacharya, Apurba,Buchanan, Charles M.,Chen, H. H.,Deyo, Don,et al.
p. 2993 - 3002
(2007/10/02)
Asymmetric Induction. Ene Reactions of a Chiral Glyoxylate Ester
The acid-catalysed reaction of 8-phenylmentol glyoxylate with hex-1-ene and trans-but-2-ene provided the ene reaction products with asymmetric induction levels consistently above 93percent.
Whitesell, James K.,Bhattacharya, Apurba,Aguilar, Daniel A.,Henke, Kevin
p. 989 - 990
(2007/10/02)
More Articles about upstream products of 108793-98-2