O-Glycosyl Imidates, 29. - Reaction of O-(Glucopyranosyl)Imidates with Electron-Rich Heterocycles. - Synthesis of C-Glucosides
The O-benzyl-protected α-glucosyl trichloroacetimidate 1 gives with furan and derivatives and ZnCl2-OEt2 as catalyst via 2-C attack the α-C-glucosides 2-α - 4-α.Good results in this reaction are also obtained with the aryl-substituted glucosyl imidate 5 a
Schmidt, Richard R.,Effenberger, Gunther
p. 825 - 832
(2007/10/02)
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