Grignard 1,4-Additions to para-Substituted (2R)-N-Cinnamoylbornane-10,2-sultam Derivatives: Revised Configuration for the N,OAc-Keteneacetal Formation in the Presence of Cu(I)
Using a19F-NMR analytical method, we have corrected and improved the linear correlation initially found between the diastereoselectivity observed during the EtMgBr conjugated addition to Michael acceptors of type 1, as a function of their σsub
Pi?tek, Anna,Chapuis, Christian
p. 573 - 582
(2016/08/25)
Diastereoselective alkyl Grignard 1,4-additions to para-substituted (2R)-N-cinnamoylbornane-10,2-sultam derivatives: Influence of N-atom pyramidalization
Several typical 13C-NMR displacements (of C=O, C(α), C(β), and Cipso), as well as conformational or energy properties (S-N-C=O dihedral angle, ΔE syn/anti; HOMO/LUMO) could be correlated with the electronic parameters of p-substitute
Piatek, Anna M.,Sadowska, Agnieszka,Chapuis, Christian,Jurczak, Janusz
p. 2141 - 2167
(2012/01/31)
Chiral γ-aryl-1H-1,2,4-triazole derivatives as highly potential antifungal agents: Design, synthesis, structure, and in vitro fungicidal activities
A novel series of chiral γ-aryl-1H-1,2,4-triazole derivatives as highly potential antifungal agents have been designed and synthesized conveniently by using the chiral auxiliary as a controlling reagent. All of the compounds exhibit moderate to high ee va
Cao, Xiufang,Li, Fei,Hu, Ming,Lu, Wenchang,Yu, Guang-Ao,Sheng, Hua Liu
experimental part
p. 11367 - 11375
(2010/03/31)
More Articles about upstream products of 1092461-45-4