Asymmetric palladium-catalyzed intramolecular α-arylation of aldehydes
(Chemical Equation Presented) Phoxy ligand: The first catalytic method for the asymmetric palladium-catalyzed intramolecular α-arylation of α-branched aldehydes was developed (see scheme). This process is distinguished by the high yields and enantioselectivities that can be obtained, making this protocol a useful synthetic tool for further applications.
Garcia-Fortanet, Jorge,Buchwald, Stephen L.
supporting information; experimental part
p. 8108 - 8111
(2009/04/13)
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