Nucleophilic Addition of Lithiated Phenyl Trimethylsilyl Sulfide to Activated Olefins. A Facile Synthesis of 2-(Functionally) Substituted Silylcyclopropanes
The lithio derivative of phenyl trimethylsilylmethyl sulfide undergoes smooth addition to activated ethylene derivatives to afford trimethylsilylcyclopropanes, except for the addition to methyl 2-phenylpropenoate which leads to the formation of methyl 4-trimethylsilyl-2-phenyl-4-(phenylthio)butanoate.
Schaumann, Ernst,Friese, Carsten,Spanka, Carsten
p. 1035 - 1037
(2007/10/02)
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