The Extremely Rapid Acid-catalysed Additions of Acetylenes to and the Synthesis of
The addition of acetylenes such as HCCH, HCCPh, or MeOOCCCCOOMe to to give 'dimetallated olefins' is catalysed by traces of acid or methanol but inhibited by a base: the 'dimetallated olefin' complex makes an interesting comparison with the vinylidene complex .
Higgins, Simon J.,Shaw, Bernard L.
p. 1629 - 1630
(2007/10/02)
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