A VERSATILE METHOD OF SYNTHESIS OF ANILINES AND CYCLOHEXENONES
Allylic cyanides are readily silylated by triisopropylsilyl chloride to give alkenyl ketenimines 1.The reaction of 1 with acetylenic dienophiles followed by desilylation leads to the formation of substituted anilines with complete regioselectivity.
Differding, Edmond,Vandevelde, Oscar,Roekens, Bertrand,Van, Tran Trieu,Ghosez, Leon
p. 397 - 400
(2007/10/02)
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