SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS V. A Stereoselective Synthesis of trans-Fused Butyrolactones.
Stereoselective rearrangement of cis-5-(4-methoxybenzyl)-spirooctan-4-ol cis-1 in acidified THF-90percent H2O2 affords 9-oxabicyclononyl hydroperoxydes 7 and 8 which are converted to medium-ring, keto-butyrolactones 2 and 3.
Ruder, Suzanne M.,Ronald, Robert C.,Lillie, Thomas S.
p. 135 - 138
(2007/10/02)
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