Arylamines constitute the core structure of many therapeutic agents, agrochemicals, and organic materials. The development of methods for the efficient and selective construction of these structural motifs from simple building blocks is desirable but stil
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Studies of Tertiary Amine Oxides. Part 8. Rearrangement of N-(2,4-Dinitrophenyl)-piperidines and -morpholine N-Oxides in Aprotic Solvents
The N-oxides of N-(2,4-dinitrophenyl)-piperidines and -morpholine undergo thermal rearrangement to the substituted hydroxylamines.The kinetics of the rearrangement were studied in aprotic solvents at four or five temperatures.Steric and polar factors have
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(2007/10/02)
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